Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato)-κ4S,N1,N1′,S′](pyridine-κN)zinc(II)
| Autor: | Oliver C. Brown, Derek A. Tocher, Philip J. Blower, Michael J. Went |
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| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 11, Pp 1349-1351 (2015) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989015019234 |
| Popis: | In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the ZnII ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis(thiosemicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular N—H...N and N—H...S hydrogen-bonding interactions extend parallel to [10-1]. |
| Databáze: | Directory of Open Access Journals |
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