Estudos de proteção da célula de saccharomyces cerevisiae para utilização em reações de redução em meio orgânico
Autor: | Nascimento Maria da Graça, Zanotto Sandra Patricia, Melegari Sílvia Pedroso, Moran Paulo J. S. |
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Jazyk: | English<br />Spanish; Castilian<br />Portuguese |
Rok vydání: | 2002 |
Předmět: | |
Zdroj: | Química Nova, Vol 25, Iss 4, Pp 567-571 (2002) |
Druh dokumentu: | article |
ISSN: | 0100-4042 1678-7064 |
Popis: | New methodologies for protection of Saccharomyces cerevisiae (FP) cells when supported in montmorillonite K10 (K10), recovered or not with gelatin (G) and in the presence or absence of sucrose (S) are presented. These systems were used for the enantioselective reduction of ethyl acetoacetate and a-chloroacetophenone in hexane, under FP/K10/G/S and FP/S at 20ºC during 24 hours, affording S-(+)-ethyl-3-hydroxybutanoate in 100% conversion and 99% ee, and R-(-)-2-chloro-1-phenylethanol 79% and 78% ee at 20 and 30 ºC, respectivelly. |
Databáze: | Directory of Open Access Journals |
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