Reaction of acyclic enaminones with methoxymethylene meldrum's acid: synthetic and structural implications

Autor: Cunha Silvio, Silva Viviane C. da, Napolitano Hamilton B., Lariucci Carlito, Vencato Ivo
Jazyk: angličtina
Rok vydání: 2003
Předmět:
Zdroj: Journal of the Brazilian Chemical Society, Vol 14, Iss 1, Pp 107-112 (2003)
Druh dokumentu: article
ISSN: 0103-5053
Popis: The reaction of acyclic enaminones with methoxymethylene Meldrum's acid afforded N-adduct and/or C-adduct of enaminones in moderate to good yields. The regiochemistry of this reaction depends on the N-amino substituent of the enaminone. The C-adduct is a precursor to 2-pyridones. X-ray analysis of two N-adducts were investigated and the Z-s-Z configuration assigned.
Databáze: Directory of Open Access Journals