Hexakis(thiourea-κS)nickel(II) nitrate: a redetermination
| Autor: | Muhammad Monim-ul-Mehboob, Mehmet Akkurt, Islam Ullah Khan, Shahzad Sharif, Iram Asif, Saeed Ahmad |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 8, Pp i57-i58 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810026668 |
| Popis: | A preliminary X-ray study of the title molecular salt, [Ni(CH4N2S)6](NO3)2, has been reported twice previously, by Maďar [Acta Cryst. (1961), 14, 894] and Rodriguez, Cubero, Vega, Morente & Vazquez [Acta Cryst. (1961), 14, 1101], using film methods. We confirm the previous studies, but to modern standards of precision and with all H atoms located. The central Ni atom (site symmetry overline{1}) of the dication is octahedrally coordinated by six S-bound thiourea molecules. The crystal structure is stabilized by intra- and intermolecular N—H...S and N—H...O hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
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