Bis[1-(4-chlorobenzyl)pyridinium] bis(1,2,5-thiadiazole-3,4-dithiolato)nickelate(II)
| Autor: | Zhi-min Wang, Fang-quan Wang, Zi-yang Liu |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 8, Pp m1143-m1143 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053681102873X |
| Popis: | The asymmetric unit of the salt, (C12H11ClN)2[Ni(C2N2S3)2], comprises one cation and a half of Ni(tdas)2 (tdas = 1,2,5-thiadiazole-3,4-dithiolate) anion. The NiII atom is located at a centre of inversion. The NiII atom has a square-planar coordination with Ni—S distances of 2.2052 (4) and 2.1970 (5) Å. In crystal, weak C—H...S and C—H...Ni contacts are observed between the anions and cations. |
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