Breakup Dynamics of Semi-dilute Polymer Solutions in a Microfluidic Flow-focusing Device

Autor: Chun-Dong Xue, Xiao-Dong Chen, Yong-Jiang Li, Guo-Qing Hu, Tun Cao, Kai-Rong Qin
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Micromachines, Vol 11, Iss 4, p 406 (2020)
Druh dokumentu: article
ISSN: 2072-666X
DOI: 10.3390/mi11040406
Popis: Droplet microfluidics involving non-Newtonian fluids is of great importance in both fundamental mechanisms and practical applications. In the present study, breakup dynamics in droplet generation of semi-dilute polymer solutions in a microfluidic flow-focusing device were experimentally investigated. We found that the filament thinning experiences a transition from a flow-driven to a capillary-driven regime, analogous to that of purely elastic fluids, while the highly elevated viscosity and complex network structures in the semi-dilute polymer solutions induce the breakup stages with a smaller power-law exponent and extensional relaxation time. It is elucidated that the elevated viscosity of the semi-dilute solution decelerates filament thinning in the flow-driven regime and the incomplete stretch of polymer molecules results in the smaller extensional relaxation time in the capillary-driven regime. These results extend the understanding of breakup dynamics in droplet generation of non-Newtonian fluids and provide guidance for microfluidic synthesis applications involving dense polymeric fluids.
Databáze: Directory of Open Access Journals