4-Methyl-N-(4-methylphenylsulfonyl)-N-[4-(4-methylphenyl)-1,3-thiazol-2-yl]benzenesulfonamide
| Autor: | Rubén M. Carballo, Simón Hernández-Ortega, Nayely Padilla-Montaño, Reyna Reyes-Martínez, Gumersindo Mirón-López |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 1, Pp o6-o7 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 05588499 |
| DOI: | 10.1107/S1600536813032145 |
| Popis: | There are two independent molecules in the asymmetric unit of the title compound, C24H22N2O4S3. In each, the sulfonamide N atoms reveal nearly a trigonal-planar geometry with two S atoms of the O=S=O groups and one C atom of the thiazole ring; the angles around the N atoms are between 117.00 (13) and 123.86 (9)°. The methylphenylsulfonyl groups are in anti conformations, forming dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)° with the trigonal S—N—S planes in the two molecules. The thiazole groups are rotated around the C—N bonds and are almost perpendicular to the S—N—S plane [dihedral angles of 78.00 (7)/72.53 (5) and 77.09 (6)/71.50 (7)°]. In the crystal, pairs of C—H...O interactions, with the O atoms of the sulfonamide groups as acceptors, link each of the independent molecules into inversion dimers. |
| Databáze: | Directory of Open Access Journals |
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