High sintering activity NaNbO3 powder synthesis via the polyacrylamide gel method and fabrication of a NaNbO3 ceramic at lower temperature

Autor: Fen Ye, Xiangping Jiang, Xiaokun Huang, Xin Nie, Chao Chen, Hao Cheng, Renfen Zeng
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Journal of Materials Research and Technology, Vol 15, Iss , Pp 5833-5840 (2021)
Druh dokumentu: article
ISSN: 2238-7854
DOI: 10.1016/j.jmrt.2021.11.030
Popis: NaNbO3 powder was synthesized via the polyacrylamide gel method, growth behaviors and associated morphology were discussed. The calcined NaNbO3 powder at 565 °C possess cubic and long columnar morphology which are NaNbO3 and Na/Nb/F or Na/Nb/F/O compounds, respectively. According to XRD and SEM, as calcined temperature raised, the amount of F in Na/Nb/F or Na/Nb/F/O compounds gradually reduced, long columnar compounds resolved into cubic NaNbO3. These changes made the NaNbO3 powder which calcined at 565 °C obtain highly sintering activity, dense NaNbO3 ceramic can sintering at 1200 °C. NaNbO3 ceramic densification was caused by the large ionic radius O2− replaced the small ionic radius F− during the calcining process. Compared with the solid–state reaction method, the sintering temperature of NaNbO3 ceramic was be reduced in this work, which contribute for low-temperature sintering technical of NaNbO3 ceramics.
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