Study of adsorption property and mechanism of lead(II) and cadmium(II) onto sulfhydryl modified attapulgite

Autor: Cheng Fu, Xiaping Zhu, Xun Dong, Ping Zhao, Zepeng Wang
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Arabian Journal of Chemistry, Vol 14, Iss 2, Pp 102960- (2021)
Druh dokumentu: article
ISSN: 1878-5352
DOI: 10.1016/j.arabjc.2020.102960
Popis: Study of the adsorption property and mechanism about the environmental functional material can provide theoretical guidance for its actual application. The sulfhydryl attapulgite (SH-ATP) was prepared by solution blending method. The saturated adsorption capacity to Pb2+ and Cd2+ in the experiment were 65.57 and 22.71 mg/g, which increased by 57.74% and 31.96% comparing with the attapulgite (ATP), respectively. The adsorption kinetics experiments illustrated that the adsorption of Pb2+ and Cd2+ onto SH-ATP accorded with multiple kinetic models. Among them, the pseudo second-order model had the best correlation, the correlation coefficients were all above 0.998. The adsorption thermodynamics experiments testified that the adsorption of Pb2+ and Cd2+ onto SH-ATP conformed to the Langmuir, Tempkin and Dubinin-Radushkevich models, those models indicated that the adsorption processes belonged to the monolayer adsorption, the adsorbent surface was homogeneous, and the micropore distribution of the adsorbent was also relatively uniform. Various thermodynamic parameters (ΔH > 0, ΔS > 0, ΔG
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