Crystal structure of fac-tricarbonyl(cyclohexyl isocyanide-κC)(quinoline-2-carboxylato-κ2N,O)rhenium(I)
| Autor: | Charalampos Triantis, Antonio Shegani, Christos Kiritsis, Catherine Raptopoulou, Vassilis Psycharis, Maria Pelecanou, Ioannis Pirmettis, Minas Papadopoulos |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 3, Pp 358-362 (2016) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989016002206 |
| Popis: | In the title compound, [Re(C10H6NO2)(C7H11N)(CO)3], the ReI atom is coordinated by three carbonyl ligands in a facial arrangement and by the N, O and C atoms from a chelating quinaldate anion and a monodentate isocyanide ligand, respectively. The resultant C4NO coordination sphere is distorted octahedral. A lengthening of the axial Re—CO bond trans to the isocyanide ligand is indicative of the trans effect. Individual complexes are stacked into rods parallel to [001] through displaced π–π interactions. Weak C—H...O hydrogen-bonding interactions between the rods lead to the formation of layers parallel to (010). These layers are stacked along [010] by C—H...H—C van der Waals contacts. |
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