Ion association with tetra-n-alkylammonium cations stabilizes higher-oxidation-state neptunium dioxocations

Autor: Shanna L. Estes, Baofu Qiao, Geng Bang Jin
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Nature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-018-07982-5
Popis: The electrochemical behaviour of redox-active metal cations foremost depends on the metal centre’s inner-sphere coordination environment. Here the authors show that electrolyte cations unexpectedly stabilize higher-oxidation-state neptunium dioxocations in water through extended-coordination sphere interactions.
Databáze: Directory of Open Access Journals