| Autor: |
Eleanora Charnetskaya, Tam D. Nguyen, Khang N. Dinh, Darcy Simondson, Sam Johnston, Carlos Felipe Garibello, Dijon A. Hoogeveen, Bernt Johannessen, Douglas R. MacFarlane, Rosalie K. Hocking, Manjunath Chatti, Alexandr N. Simonov |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
Advanced Energy & Sustainability Research, Vol 4, Iss 11, Pp n/a-n/a (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2699-9412 |
| DOI: |
10.1002/aesr.202300108 |
| Popis: |
When used to promote the oxygen evolution reaction (OER), transition‐metal chalcogenides convert into oxyhydroxide/(hydr)oxide catalysts, the performance of which depends on the properties of the precursor. The present study aims to explore these effects for cobalt and cobalt–iron selenides (CoSe n and Co1Fe1Se n ) prepared using a simple microwave‐assisted method, in comparison to a reference material synthesized by high‐temperature reaction of CoO x H y with Se vapors. Physical characterization of the microwave‐synthesized CoSe n demonstrates their sheet‐like morphology and identifies Co3Se4 as the major phase, which is essentially completely transformed into CoOOH during the OER. The temperature during the microwave‐assisted CoSe n synthesis affects the crystallinity, the electrochemically active surface area, and thereby the performance of the resulting catalysts. Further improvements in the activity are achieved by combining cobalt with iron into a bimetallic Co1Fe1Se n precursor, which transforms in situ into a CoOOH + FeOOH composite and sustains the OER rate of 100 mA cm−2 (33 A g−1) at an overpotential of ≈ 0.31 and 0.26 V at 24 ± 2 and 80 ± 1 °C, respectively. Satisfactory stability of the Co1Fe1Se n ‐derived electrodes is demonstrated through a 4‐day‐long test at 80 ± 1 °C and 100 mA cm−2. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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