Chlorido(2-{(2-hydroxyethyl)[tris(hydroxymethyl)methyl]amino}ethanolato-κ5N,O,O′,O′′,O′′′)copper(II)

Autor:	Monserrat Fortis-Valera, Rosa Elena Arroyo-Carmona, Aarón Pérez-Benítez, Sylvain Bernès
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	crystal structure coordination compound bis-tris supramolecular structure very strong hydrogen bonds Crystallography QD901-999
Zdroj:	IUCrData, Vol 9, Iss 5, p x240439 (2024)
Druh dokumentu:	article
ISSN:	2414-3146 24143146
DOI:	10.1107/S2414314624004395
Popis:	The title complex, [Cu(C8H18NO5)Cl] or [Cu(H4bis-tris)Cl], was obtained starting from the previously reported [Cu(H5bis-tris)Cl]Cl compound. The deprotonation of the aminopolyol ligand H5bis-tris {[bis(2-hydroxyethyl)amino]tris(hydroxymethyl)methane, C8H19NO5} promotes the formation of a very strong O—H...O intermolecular hydrogen bond, characterized by an H...O separation of 1.553 (19) Å and an O—H...O angle of 178 (4)°. The remaining hydroxy groups are also engaged in hydrogen bonds, forming R22(8), R44(16), R44(20) and R44(22) ring motifs, which stabilize the triperiodic supramolecular network.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/d32d286731e0436d814349cd3ad0356f Zobrazit plný text záznamu View record in DOAJ