Long-term electrochemical characterization of novel Sr2FeMo0.65Ni0.35O6−δ fuel electrode for high-temperature steam electrolysis in solid oxide cells

Autor: Stephanie E. Wolf, Vaibhav Vibhu, Pritam K. Chakraborty, Shibabrata Basak, Izaak C. Vinke, L.G.J. (Bert) de Haart, Rüdiger-A. Eichel
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Electrochemistry Communications, Vol 167, Iss , Pp 107799- (2024)
Druh dokumentu: article
ISSN: 1388-2481
DOI: 10.1016/j.elecom.2024.107799
Popis: The present study focuses on the highly catalytic double-perovskite Sr2FeMo0.65Ni0.35O6−δ (SFMNi) fuel electrode material for Solid Oxide Electrolysis Cells (SOECs). The electrolyte-supported single button cells with the highly active SFMNi fuel electrode were electrochemically characterized between 900 °C down to 750 °C in steam and co-electrolysis conditions using DC- and AC-techniques. The cells achieved current densities of −1.62 A cm−2 and −1.74 A cm−2 at 900 °C under steam and co-electrolysis conditions, respectively, exceeding the performance of cells with Ni-8YSZ fuel electrodes by ∼65–79 % and Ni-GDC fuel electrodes by 24–28 %. The post-test SEM-EDX analyses of the as-prepared and tested cells’ cross-section showed increased pore formation and particle growth of the SFMNi fuel electrode after testing in the humidified atmosphere for 500 h.
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