trans-Bis[1,2-bis(diphenylphosphanyl)ethane]chlorido(ethynyl)ruthenium(II)
| Autor: | Alexander Trujillo, Mauricio Fuentealba, Ramiro Arratia-Perez, Judith A. K. Howard |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 12, Pp m1445-m1445 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812044558 |
| Popis: | The molecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2], consists of an RuII cation, located on an inversion centre, in an octahedral environment defined by two chelating phosphines, one acetylide and one chloride ligand. The –C[triple-bond]CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octahedral, with the –C[triple-bond]CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octahedron and the chloride and acetylide ligands the axial positions. |
| Databáze: | Directory of Open Access Journals |
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