Autor: |
Artem A. Lobinsky, Maria V. Kaneva, Maxim I. Tenevich, Vadim I. Popkov |
Jazyk: |
angličtina |
Rok vydání: |
2023 |
Předmět: |
|
Zdroj: |
Micromachines, Vol 14, Iss 5, p 1083 (2023) |
Druh dokumentu: |
article |
ISSN: |
2072-666X |
DOI: |
10.3390/mi14051083 |
Popis: |
Rechargeable metal-ion batteries (RMIBs) are prospective highly effective and low-cost devices for energy storage. Prussian blue analogues (PBAs) have become a subject of significant interest for commercial applications owing to their exceptional specific capacity and broad operational potential window as cathode materials for rechargeable metal-ion batteries. However, the limiting factors for its widespread use are its poor electrical conductivity and stability. The present study describes the direct and simple synthesis of 2D nanosheets of MnFCN (Mn3[Fe(CN)6]2·nH2O) on nickel foam (NF) via a successive ionic layer deposition (SILD) method, which provided more ion diffusion and electrochemical conductivity. MnFCN/NF exhibited exceptional cathode performance for RMIBs, delivering a high specific capacity of 1032 F/g at 1 A/g in an aqueous 1M NaOH electrolyte. Additionally, the specific capacitance reached the remarkable levels of 327.5 F/g at 1 A/g and 230 F/g at 0.1 A/g in 1M Na2SO4 and 1M ZnSO4 aqueous solutions, respectively. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
|