| Autor: |
Wenjin Ding, Yuan Shi, Markus Braun, Fiona Kessel, Martin Frieß, Alexander Bonk, Thomas Bauer |
| Jazyk: |
angličtina |
| Rok vydání: |
2021 |
| Předmět: |
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| Zdroj: |
Energies, Vol 14, Iss 9, p 2599 (2021) |
| Druh dokumentu: |
article |
| ISSN: |
1996-1073 |
| DOI: |
10.3390/en14092599 |
| Popis: |
Oxide ceramics could be attractive high-temperature construction materials for critical structural parts in high-temperature molten salt thermal energy storage systems due to their excellent corrosion resistance and good mechanical properties. The 3D-printing technology allows the production of ceramic components with highly complex geometries, and therefore extends their applications. In this work, 3D-printed ZrO2 and Al2O3 ceramics were immersed in molten MgCl2/KCl/NaCl under argon or exposed in argon without molten chlorides at 700 °C for 600 h. Their material properties and microstructure were investigated through three-point-bend (3PB) testing and material analysis with SEM-EDX and XRD. The results show that the 3D-printed Al2O3 maintained its mechanical property after exposure in the strongly corrosive molten chloride salt. The 3D-printed ZrO2 had an enhanced 3PB strength after molten salt exposure, whereas no change was observed after exposure in argon at 700 °C. The material analysis shows that some of the ZrO2 on the sample surface changed its crystal structure and shape (T→M phase transformation) after molten salt exposure, which could be the reason for the enhanced 3PB strength. The thermodynamic calculation shows that the T→M transformation could be caused by the reaction of the Y2O3-stabilized ZrO2 with MgCl2 (mainly Y2O3 and ZrO2 with gaseous MgCl2). In conclusion, the 3D-printed ZrO2 and Al2O3 ceramics have excellent compatibility with corrosive molten chlorides at high temperatures and thus show a sound application potential as construction materials for molten chlorides. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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