Methyl 2-[(Z)-5-methyl-2-oxoindolin-3-ylidene]hydrazinecarbodithioate

Autor: Mohd Abdul Fatah Abdul Manan, David B. Cordes, Aidan P. McKay
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: IUCrData, Vol 9, Iss 10, p x240967 (2024)
Druh dokumentu: article
ISSN: 2414-3146
24143146
DOI: 10.1107/S2414314624009672
Popis: The title dithiocarbazate imine, C11H11N3OS2, was obtained from the condensation reaction of S-methyldithiocarbazate (SMDTC) and 5-methylisatin. It shows a Z configuration about the imine C=N bond, which is associated with an intramolecular N—H...O hydrogen bond that closes an S(6) ring. In the crystal, inversion dimers linked by pairwise N—H...O hydrogen bonds generate R22(8) loops. The extended structure features C—H...S contacts as well as reciprocal carbonyl–carbonyl (C=O...C=O) interactions.
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