N,N′-Bis(3-ethoxy-2-hydroxybenzylidene)-phenylene-1,3-diamine Methanol Solvate

Autor:	Dariusz Osypiuk, Agata Bartyzel, Beata Cristóvão
Jazyk:	angličtina
Rok vydání:	2023
Předmět:	multisite Schiff base thermal stability N2O4 compartmental ligand salen ligand Inorganic chemistry QD146-197
Zdroj:	Molbank, Vol 2023, Iss 3, p M1688 (2023)
Druh dokumentu:	article
ISSN:	1422-8599
DOI:	10.3390/M1688
Popis:	A crystal structure and thermal characterization of a multisite Schiff base containing N2O2-inner and O4-outer coordination sites are reported. The title compound was characterized by X-ray structure analysis, 1H-NMR, 13C-NMR and ATR-FTIR spectroscopy, TG/DSC and TG-FTIR techniques. The compound crystallizes as a methanol solvate in the triclinic system, space group P1¯. The stable at room temperature compound, during heating in the air, first loses a methanol molecule. At higher temperature, the sample decomposition is associated with a strong exothermic effect and the emission of large amounts of carbon dioxide, carbon monoxide and ammonia.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/31716366c84d439e9f3af91483db1895 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
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