(tert-Butyl isocyanide-κC)trichloridogallium(III)

Autor:	Jeremy L. Bourque, Nada Y. Tashkandi, Kim M. Baines
Jazyk:	angličtina
Rok vydání:	2016
Předmět:	crystal structure isocyanide complexes Lewis acid–base complex gallium trichloride Crystallography QD901-999
Zdroj:	IUCrData, Vol 1, Iss 3, p x160389 (2016)
Druh dokumentu:	article
ISSN:	2414-3146 24143146
DOI:	10.1107/S2414314616003898
Popis:	The crystal structure of (tert-butyl isocyanide-κC)trichloridogallium(III), [GaCl3(C5H9N)], features the first reported isocyanide–gallium trihalide complex. The Ga—C—N—C fragment is essentially linear. The methyl fragments of the tert-butyl group are eclipsed with the chloride ligands on the Ga atom. The molecule does not, however, exhibit threefold crystallographic symmetry, as it crystallizes within the P21/c space group.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/e30d24fb531243e9b9613ab999ab14b7 Zobrazit plný text záznamu View record in DOAJ