Cyclopalladated Compounds with Bulky Phosphine (dppm): Synthesis, Characterization, and X-ray Diffraction
| Autor: | Basma Al Janabi, Juan M. Ortigueira, Jose Manuel Vila |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Chemistry Proceedings, Vol 12, Iss 1, p 35 (2022) |
| Druh dokumentu: | article |
| ISSN: | 2673-4583 |
| DOI: | 10.3390/ecsoc-26-13563 |
| Popis: | The reaction between a cholro-bridged dinuclear compound (a, b) and a diphosphine (dppm) ligand in a molar ratio of 1:2 yielded a mononuclear compound [{Pd[R-C6H3C(H)=NCy]{Ph2PCH2PPh2-P,P}][PF6] {R = 3-CHO (1a), 4-CHO (1b)}. The compounds were characterized using IR, 1H, and 31P–{1H} NMR spectroscopy, and compound 1b was identified using X-ray diffraction. |
| Databáze: | Directory of Open Access Journals |
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