Photochemical Properties of Precipitated Titania Aerosol Produced by Powdering of Crystal Rutile under Ambient Air

Autor: Valery Zakharenko, Alexey Filimonov
Jazyk: angličtina
Rok vydání: 2013
Předmět:
Zdroj: Journal of Chemistry, Vol 2013 (2013)
Druh dokumentu: article
ISSN: 2090-9063
2090-9071
DOI: 10.1155/2013/614724
Popis: It is shown that the quantum yields of oxygen photoadsorption and carbon dioxide photodesorption on TiO2 are significantly higher under illumination by quanta with energy from the surface absorption region of TiO2 when it is not produced by the traditional way, but from the rutile crystal. The magnitudes and spectral dependencies of the quantum yield of photoadsorption and photodesorption for TiO2 produced from a monocrystal are determined. A mechanism of a sharp increase of the titania photoadsorption activity in the surface absorption region is proposed.
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