Corrosion Behavior and Mechanical Properties of Zn–Ti Alloys as Biodegradable Materials

Autor: Alexandra-Tamara Șutic, Romeu Chelariu, Ramona Cimpoeșu, Ana-Maria Roman, Bogdan Istrate, Viorel Goanță, Marcelin Benchea, Mihaela Moscu, Adrian Alexandru, Nicanor Cimpoeşu, Georgeta Zegan
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Metals, Vol 14, Iss 7, p 764 (2024)
Druh dokumentu: article
ISSN: 2075-4701
DOI: 10.3390/met14070764
Popis: The influence of the chemical composition and structural state of Zn–Ti alloys on corrosion behaviour and mechanical properties was studied. Zn-based alloys were investigated, more precisely, pure technical Zn and Zn with 0.10, 0.25 and 1.00 wt.% Ti. The microstructure and chemical composition of these materials were analysed using light optical microscopy (LOM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD). The chemical composition of the alloys and the surface after immersion were analysed using an EDS detector from Bruker. The alloys’ electro-chemical corrosion resistance was further investigated through linear (LP) and cyclic (CP) potentiometry and open-circuit potential (OCP) analysis. A tensile/compression equipment (Instron 34SC-5) was used to determine the compression behaviour. UMT testing equipment was used to determine microhardness (by Rockwell indentation) and COF vs. length. For percentages higher than 0.25 wt.% Ti, the formation of a primary TiZn16 intermetallic compound in the (α-Zn + TiZn16) eutectic matrix was observed, a slight influence of TiZn16 on the Zn corrosion resistance results, and a greater influence on the mechanical properties was confirmed.
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