Synthesis and Photovoltaic Performance of β-Amino-Substituted Porphyrin Derivatives

Autor:	Ana F. R. Cerqueira, Ana Lucia Pinto, Gabriela Malta, Maria G. P. M. S. Neves, A. Jorge Parola, Augusto C. Tomé
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	porphyrins nucleophilic aromatic substitution thiols dye-sensitized solar cells power conversion efficiency Biology (General) QH301-705.5 Chemistry QD1-999
Zdroj:	International Journal of Molecular Sciences, Vol 25, Iss 11, p 5979 (2024)
Druh dokumentu:	article
ISSN:	25115979 1422-0067 1661-6596
DOI:	10.3390/ijms25115979
Popis:	New β-amino-substituted porphyrin derivatives bearing carboxy groups were synthesized and their performance as sensitizers in dye-sensitized solar cells (DSSC) was evaluated. The new compounds were obtained in good yields (63–74%) through nucleophilic aromatic substitution reactions with 3-sulfanyl- and 4-sulfanylbenzoic acids. Although the electrochemical studies indicated suitable HOMO and LUMO energy levels for use in DSSC, the devices fabricated with these compounds revealed a low power conversion efficiency (PCE) that is primarily due to the low open-circuit voltage (Voc) and short-circuit current density (Jsc) values.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/d2d6cb63d5cf4f729b27e8a1a784354d Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
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