Green synthesis of cyclohexanone to adipic acid over Fe–W oxides incorporated mesoporous carbon support

Autor: Siva Prasad Mekala, Marimuthu Prabu, Sheetal Datta Gawali, Karthik Gopakumar, Pranjal Gogoi, Akash Ravindra Bhatkar, Gourab Mohapatra, Eeswar Unnikrishanan, Thirumalaiswamy Raja
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Catalysis Communications, Vol 168, Iss , Pp 106466- (2022)
Druh dokumentu: article
ISSN: 1873-3905
DOI: 10.1016/j.catcom.2022.106466
Popis: We have prepared iron and tungsten oxides incorporated mesoporous carbon (MC) catalysts using a simple hydrothermal methodology with different carbon sources, and the catalytic performance was investigated for cyclohexanone oxidation. An adequate amount of metal oxide loading has displayed a key role in the selective catalyst for adipic acid (AA) synthesis. The MC catalyst has shown its prime activity under the influence of redox properties of W5+/W6+ and Fe2+/Fe3+ as promoters. The 10%Fe 90%W-MC fructose as a carbon source catalyst has provided its best selectivity of 87% for AA at 120 °C.
Databáze: Directory of Open Access Journals