| Autor: |
Usama Zafar, Prince Kumar Rai, Ankur Gupta, Jan G. Korvink, Vlad Badilita, Monsur Islam |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
C, Vol 10, Iss 2, p 28 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2311-5629 |
| DOI: |
10.3390/c10020028 |
| Popis: |
This work presents anodically electrodeposited copper (Cu)/chitosan gel as a novel precursor for synthesizing a Cu/carbon nanocomposite through laser-induced carbonization. Metal/carbon nanocomposites offering advantageous properties compared to their individual counterparts stand out in various applications, particularly in those involving electrochemical phenomena. However, their synthesis often suffers from complicated and time-consuming synthesis procedures. Here, we integrate anodic electrodeposition and laser-induced carbonization to yield a rapid, simple, and inexpensive procedure for synthesizing metal/carbon nanocomposite. A precursor composite involving Cu-coordinated chitosan film is achieved through anodic electrodeposition on a copper anode. Irradiation by an infrared laser with optimized parameters results in the thermochemical decomposition of the Cu/chitosan composite, rapidly forming a nanocomposite material featuring highly graphitized and porous carbon materials. Elemental mapping confirms the formation of the nanocomposite, although no crystalline phases of copper are observed during X-ray diffraction. This can be attributed to the rapid nature of the laser-carbonization process. The nanocomposite material is further demonstrated for electrochemical sensing of hydrogen peroxide (H2O2), exhibiting a sensitivity of 2.65 mM−1 for concentrations ranging from 0.01 mM to 0.1 mM H2O2, and 0.01 ± 0.01 mM−1 for concentrations from 0.1 to 10 mM H2O2. These sensitivities are comparable to other non-enzymatic H2O2 biosensors. The finding of this work signifies a rapid and facile method for synthesizing metal/carbon nanocomposites with strong implications for the field of biosensors. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
|
