Synthesis and crystal structure of a 4,4’-bipyridine linked dinuclear copper(II) complex derived from 2-{[2-(2-hydroxyethylamino)ethylimino]methyl}-6-methylphenol
| Autor: | Hai-Liang Zhu, Xiu-Zhen Zhang, Yitong Gu, Andong Liu, Fuyao Liu, Zhonglu You, Yuntong Li |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Acta Chimica Slovenica, Vol 63, Iss 4, Pp 721-725 (2016) |
| Druh dokumentu: | article |
| ISSN: | 1318-0207 1580-3155 |
| DOI: | 10.17344/acsi.2016.2421 |
| Popis: | A novel 4,4'-bipyridine linked dinuclear copper(II) complex, [Cu2L2(bipy)](NO3)2·bipy (L = 2-{[2-(2-hydroxyethylamino)ethylimino]methyl}-6-methylphenol; bipy = 4,4'-bipyridine), was prepared and characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction. The Cu∙∙∙Cu distance is 11.129(2) Å. The CuII atom is coordinated by one phenolate O, one imine N, and one amine N atoms of a Schiff base ligand, and one N atom of the bridging 4,4'-bipyridine ligand, forming a square planar geometry. In the crystal structure of the complex, the dinuclear copper complex cations are linked by 4,4'-bipyridine molecules through intermolecular O–H···N hydrogen bonds, to form 1D chains running in the [2 0 –1] direction. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|