(2,2′-Bipyridine-κ2N,N′)(4,4′-dimethoxy-2,2′-bipyridine-κ2N,N′)palladium(II) bis(trifluoromethanesulfonate)

Autor:	Brittney B. Vargas, Hadi D. Arman, Rafael A. Adrian
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	crystal structure palladium(ii) complex square-planar coordination environment 2 2′-bipyridine 4 4′-dimethoxy-2 2′-bipyridine trifluoromethanesulfonate salt τ4 descriptor Crystallography QD901-999
Zdroj:	IUCrData, Vol 9, Iss 2, p x240109 (2024)
Druh dokumentu:	article
ISSN:	2414-3146 24143146
DOI:	10.1107/S2414314624001093
Popis:	In the title complex salt, [Pd(C10H8N2)(C12H12N2O2)](CF3SO3)2, the palladium(II) atom is fourfold coordinated by two chelating ligands, 2,2′-bipyridine and 4,4′-dimethoxy-2,2′-bipyridine, in a distorted square-planar environment. In the crystal, weak π–π stacking interactions between the 2,2′-bipyridine rings [centroid-to-centroid distances = 3.8984 (19) Å] and between the 4,4′-dimethoxy-2,2′-bipyridine rings [centroid-to-centroid distances = 3.747 (18) Å] contribute to the alignment of the complex cations in columns parallel to the b-axis direction.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/29878fd9f8bf45dd97822378b779f6b2 Zobrazit plný text záznamu View record in DOAJ