APPLICATION OF NMR IN THE INVESTIGATION OF DYNAMIC TAUTOMERISM OF 4(3H)-QUINAZOLINONE SYSTEM
Autor: | Pham Thi Thanh My, Chu Dinh Kinh, Thanh Thi Thu Thuy, Nguyen Ngoc Vinh, Nguyen Thi Phuong Chi |
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Jazyk: | angličtina |
Rok vydání: | 2017 |
Předmět: | |
Zdroj: | ASEAN Journal on Science and Technology for Development, Vol 25, Iss 2, Pp 445-455 (2017) |
Druh dokumentu: | article |
ISSN: | 0217-5460 2224-9028 |
DOI: | 10.29037/ajstd.275 |
Popis: | Tautomerism of 4(3H)-quinazolinone system with [(2-hydroxyphenyl)methylene]-2-(4oxoquinazolin-3(4H)-yl)acetohydrazide and N’-[(1E)-(4-hydroxy-3-methoxyphenyl)methylene]-2-(4-oxoquinazolin-3(4H)-yl)acetohydrazide as two representative compounds was investigated on the basis of 1H NMR method at coalescence with the help of line formprogramme. The dynamic parameters such as k, Ea, DG*, DH*, DS* were fully calculated with high reliability. |
Databáze: | Directory of Open Access Journals |
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