| Autor: |
Rumeng Xu, Chunchun Yin, Jingxuan You, Jinming Zhang, Qinyong Mi, Jin Wu, Jun Zhang |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
Green Energy & Environment, Vol 9, Iss 5, Pp 927-936 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2468-0257 |
| DOI: |
10.1016/j.gee.2022.10.009 |
| Popis: |
Non-degradable polymers cause serious environmental pollution problem, such as the widely-used while unrecyclable coatings which significantly affect the overall degradation performance of products. It is imperative and attractive to develop biodegradable functional coatings. Herein, we proposed a novel strategy to successfully prepare biodegradable, thermoplastic and hydrophobic coatings with high transparence and biosafety by weakening the interchain interactions between cellulose chain. The natural cellulose and cinnamic acid were as raw materials. Via reducing the degree of polymerization (DP) of cellulose and regulating the degree of substitution (DS) of cinnamate moiety, the obtained cellulose cinnamate (CC) exhibited not only the thermal flow behavior but also good biodegradability, which solves the conflict between the thermoplasticity and biodegradability in cellulose-based materials. The glass transition temperature (Tg) and thermal flow temperature (Tf) of the CC could be adjusted in a range of 150–200 °C and 180–210 °C, respectively. The CC with DS |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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