Poly[(μ5-2,2′-bipyridine-5,5′-dicarboxylato)lead(II)]

Autor: Mustafa Sertçelik, Nagihan Çaylak Delibaş, Sabri Çevik, Hacali Necefoğlu, Tuncer Hökelek
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 68, Iss 9, Pp m1196-m1197 (2012)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536812035647
Popis: In the title polymeric compound, [Pb(C12H6N2O4)]n, the PbII cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′-dicarboxylate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N2O6 geometry. The carboxylate groups bridge the PbII cations, forming a three-dimensional polymeric structure. The carboxylate group is twisted away from the attached pyridine ring by 11.4 (3)°.
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