2,6-Bis[bis(1,1-dimethylethyl)phosphinito-κP]phenyl-κC]-trans-chlorohydro(phenylphosphine)iridium(III)

Autor: Neil T. Mucha, Rory Waterman
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Molbank, Vol 2022, Iss 2, p M1388 (2022)
Druh dokumentu: article
ISSN: 1422-8599
DOI: 10.3390/M1388
Popis: The molecular structure of an iridium complex featuring a phenylphosphine ligand is described. The reaction of (POCOP)IrHCl (1, POCOP = 2,6-(tBu2PO)2C6H3–) with phenylphosphine gives (POCOP)IrHCl(PH2Ph) (2) under mild conditions. The structural features are consistent with a classic pseudo-octahedral iridium compound with three neutral phosphine donors. Compound 1 is unreactive at elevated temperatures and is unreactive toward excess phenylphosphine under the sampled conditions.
Databáze: Directory of Open Access Journals
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