Enantioselective Formation of Amino Acids by Isomerization of Mixed Ligand Copper(ll) Schiff-Base Complexes
| Autor: | Thierry Chuard, François Gretillat, Klaus Bernauer |
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| Jazyk: | German<br />English<br />French |
| Rok vydání: | 1993 |
| Předmět: | |
| Zdroj: | CHIMIA, Vol 47, Iss 6 (1993) |
| Druh dokumentu: | article |
| ISSN: | 0009-4293 2673-2424 |
| Popis: | The formation of optically active phenylalanine from phenylpyruvic acid and pyridoxamine in the presence of various chiral CuII complexes was investigated as a function of the reaction conditions. The enantioselectivity of the reaction, as well as the pH- and ligand-dependant racemization of the product, is discussed in terms of possible reaction pathways and the most likely structure of intermediate [Cu(L)aldimine] complexes. |
| Databáze: | Directory of Open Access Journals |
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