The effect of solvent on the kinetics of the oxidation of benzaldehydes by quinolinium chlorochromate in aqueous organic solvent media

Autor:	Jeyanthi Fatima G., Vijayakiiinarand G., Elango K.P.
Jazyk:	angličtina
Rok vydání:	2002
Předmět:	kinetics solvent effect structural effect benzaldehyde oxidation. Chemistry QD1-999
Zdroj:	Journal of the Serbian Chemical Society, Vol 67, Iss 12, Pp 803-808 (2002)
Druh dokumentu:	article
ISSN:	0352-5139 1820-7421
DOI:	10.2298/JSC0212803J
Popis:	The kinetics of the oxidation of benzaldehyde and para-substituted benzaldehydes by quinolinium chlorochromate in water-dimethylformamide mixtures has been studied under pseudo-first-order conditions at 25±0.2ºC. The operation of non-specific and specific solvent-solute interactions was explored by correlating the rate data with solvent parameters through a correlation analysis technique. Both electron-releasing and electron-withdrawing substitutents enhance the rate of oxidation and the Hammett plot shows a break in the reactivity order indicating the applicability of a dual mechanism.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/26f77fc505e34cb69881e0f83a4e0857 Zobrazit plný text záznamu View record in DOAJ