Control of Ni/Ce1-xMxOy Catalyst Properties Via the Selection of Dopant M = Gd, La, Mg. Part 2. Catalytic Activity
| Autor: | M. A. Kerzhentsev, E. V. Matus, I. Z. Ismagilov, O. B. Sukhova, P. Bharali, Z. R. Ismagilov |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | Eurasian Chemico-Technological Journal, Vol 20, Iss 4, Pp 293-300 (2018) |
| Druh dokumentu: | article |
| ISSN: | 1562-3920 2522-4867 |
| DOI: | 10.18321/ectj762 |
| Popis: | To elucidate the role of support composition in autothermal reforming of ethanol (ATR of C2H5OH), a series of Ni catalysts (Ni content 2–15 wt.%) supported on different ceria-based oxides (Ce1-xGdxOy, Ce1-xLaxOy and Ce1-xMgxOy; x = 0.1–0.9) were prepared. The synthetized materials were tested in ATR of ethanol at 200–700 °C. It was established that supports themselves show catalytic activity in ATR of C2H5OH and provide 10–15% yield of H2 at 700 °C. Upon the increase of Ni content from 2 to 15 wt.% the temperature of 100% ethanol conversion decreases from 700 tо 300 °С, hydrogen yield increases from 25 to 60%, the inhibition of С2-С3 by-products formation, as well as the promotion of decomposition of acetaldehyde occur. The enhancement of catalyst performance in ATR of C2H5OH has been observed in the next series of supports: Ce1-xMgxOy < Ce1-xGdxOy < Ce1-xLaxOy and with a decrease of x to an optimal value that correlates with the improvement of Ni active component reducibility. At 600 °C on 10Ni/Ce0.8La0.2O1.9 catalyst the H2 yield of 50% was achieved at C2H5OH conversion of 100%. Stable and high performance of developed catalysts in ATR of C2H5OH indicates the promise of their use in the production of hydrogen. |
| Databáze: | Directory of Open Access Journals |
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