S, N co-doped pitch-based composite carbon nanofibers with enlarged interlayer distance as a superior potassium ion batteries anode

Autor: Liu Chang, Song Ze, Ma Tianyi, Qiu Jieshan
Jazyk: English<br />French
Rok vydání: 2020
Předmět:
Zdroj: E3S Web of Conferences, Vol 213, p 02003 (2020)
Druh dokumentu: article
ISSN: 2267-1242
DOI: 10.1051/e3sconf/202021302003
Popis: Potassium ion batteries (PIBs), an alternative to traditional lithium ion batteries to large-scale energy storage device, have attracted tremendous attention, due to abundant reserves of potassium resources and low cost. However, it still remains challenge to fabricate suitable anode materials with high K storage capabilities. In this work, facile S/N co-doped pitch based composite carbon nanofibers has been fabricated by electrospinning of coal tar pitch and polyacrylonitrile, and followed by carbonization under H2S/Ar atmosphere. The formation of -C-S-Cbond effectively increased S utilization, and enlarged carbon interlayer distance to some degree. As anode for PIBs, the S/N co-doped carbon displayed enhancement of capacity, rate capability and cycle stability. This work would shed a light on the fabrication of S/N co-doped materials for both battery, supercapacitor and electrocatalytic electrodes.
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