Dominant Effect of Heterogeneous Dynamics on Homogenous Crystal Nucleation in Supercooled Liquids

Autor: Edgar D. Zanotto, Maziar Montazerian
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Frontiers in Physics, Vol 8 (2020)
Druh dokumentu: article
ISSN: 2296-424X
25492888
DOI: 10.3389/fphy.2020.00020
Popis: Understanding the microscopic (molecular) mechanism of crystal nucleation remains intangible. For instance, it is still impossible to predict in which regions of a supercooled liquid nucleation will occur. Moreover, allegedly the Classical Nucleation Theory fails to describe the homogeneous crystal nucleation rates below the glass transition temperature. In this mini-review article, we revisit, critically comment, and link some highly selected recent studies using examples of an oxide glass-former, water, and a metallic alloy on the largely neglected effect of dynamic heterogeneities on crystal nucleation.
Databáze: Directory of Open Access Journals