Preparation and Characterization of 2-(Methylamino) Pyridine Complex of Cu(I)

Autor: Hossein Aghabozorg, Hassan Hosseini Monfared
Jazyk: angličtina
Rok vydání: 1995
Předmět:
Zdroj: Iranian Journal of Chemistry & Chemical Engineering, Vol 14, Iss 1, Pp 6-9 (1995)
Druh dokumentu: article
ISSN: 1021-9986
Popis: 2-(Methylamino) pyridine (HMAP) reacts with MeLi in THF and generates the lithium salt (LiMAP). Further reaction of [Cu(TMEDS)2][CuCl2] (TMEDA=tetramethylethylenediamine) with one equivalent of this ligand in THF leads to the formation of a yellow dimeric Cu(I) complex, [Cu(MAP)]2. Analytical data, molecular weight, and magnetic susceptibility measurements, confirm the formula [Cu(MAP)]2 .
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