| Autor: |
Ningyu Liu, Matthew D. Sleck, William D. Jones |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Chemistry, Vol 5, Iss 4, Pp 2056-2067 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2624-8549 |
| DOI: |
10.3390/chemistry5040139 |
| Popis: |
A single-step method for aniline formation was examined. Using a vanadate catalyst with an iron oxide co-catalyst and hydroxylamine hydrochloride as the amine source, an up to 90% yield of aniline was obtained with high selectivity. Further study showed that the overall reaction was pseudo-second order in terms of hydroxylamine concentration. Regioselective H-D exchange experiments suggest that the C-N bond formation step occurs via an irreversible electrophilic pathway. Based on all of the key observations, a mechanism is proposed. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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