CuO-catalyzed conversion of arylacetic acids into aromatic nitriles with K4Fe(CN)6 as the nitrogen source

Autor: Ai-Ping Xing, Zhenpeng Shen, Zhe Zhao, Xinzhe Tian, Yun-Lai Ren
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Catalysis Communications, Vol 149, Iss , Pp 106175- (2021)
Druh dokumentu: article
ISSN: 1873-3905
DOI: 10.1016/j.catcom.2020.106175
Popis: Readily available CuO was demonstrated to be effective as the catalyst for the conversion of arylacetic acids to aromatic nitriles with non-toxic and inexpensive K4Fe(CN)6 as the nitrogen source via the complete cleavage of the CN triple bond. The present method allowed a series of arylacetic acids including phenylacetic acids, naphthaleneacetic acids, 2-thiopheneacetic acid and 2-furanacetic acid to be converted into the targeted products in low to high yields.
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