Ion-Exchange Membranes Based on Polynorbornenes with Fluorinated Imide Side Chain Groups
Autor: | Arlette A. Santiago, Joel Vargas, Mikhail A. Tlenkopatchev, Mar López-González, Evaristo Riande |
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Jazyk: | angličtina |
Rok vydání: | 2012 |
Předmět: | |
Zdroj: | International Journal of Chemical Engineering, Vol 2012 (2012) |
Druh dokumentu: | article |
ISSN: | 1687-806X 1687-8078 |
DOI: | 10.1155/2012/835378 |
Popis: | The electrochemical characteristics of cation-exchange membranes based on polynorbornenes with fluorinated and sulfonated dicarboximide side chain groups were reported. This study was extended to a block copolymer containing structural units with phenyl and 4-oxybenzenesulfonic acid, 2,3,5,6-tetrafluorophenyl moieties replacing the hydrogen atom of the dicarboximide group. A thorough study on the electrochemical characteristics of the membranes involving electromotive forces of concentration cells and proton conductivity is reported. The proton permselectivity of the membranes is also discussed. |
Databáze: | Directory of Open Access Journals |
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