Fabrication and characterization of graphene oxide/zirconium dioxide coatings produced by plasma electrolytic oxidation of Zr–1%Nb alloys

Autor: Meysam Karimi, Mohammad Jafari Eskandari, Masoud Araghchi
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Results in Surfaces and Interfaces, Vol 14, Iss , Pp 100205- (2024)
Druh dokumentu: article
ISSN: 2666-8459
DOI: 10.1016/j.rsurfi.2024.100205
Popis: In this investigation, a graphene oxide (GO)/zirconium dioxide (ZrO2) composite coating was fabricated on Zr–1%Nb alloy by plasma electrolytic oxidation (PEO) process to improve the wear behavior and reduce friction performance of the Zr alloy. The GO-containing composite coating was mainly composed of the monoclinic (m-ZrO2) and tetragonal (t-ZrO2) phases and had a higher intensity of surface reactions, density, and thickness than the GO-free coating. Furthermore, the GO-containing coating exhibited lower icorr and more positive Ecorr than the GO-free coating. The optimal amount of GO sheets for improving the composite coating properties was found to be 2 wt%; use of more than 2 wt% of the GO sheets, however reduced the coating properties due to the increase in the conductivity of the electrolyte, the creation of stronger micro-discharges on the surface of the coating, and their aggregation. Additionally, the GO sheets improved the hydrophobicity of the PEO coating.
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