(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) bis[O,O′-bis(4-methylphenyl) thiophosphate]
| Autor: | Chuan Lai, Jian-Shen Feng, Li-Ke Zou, Bin Xie, Yang-Guang Xiang |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 1, Pp m59-m59 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810051184 |
| Popis: | In the centrosymmetric title complex, [Ni(C16H36N4)](C14H14O3PS)2, the NiII ion is coordinated by four N atoms and two O atoms within a slightly distorted NiN4O2 octahedral geometry. The asymmetric unit consits of one NiII ion that is located on a center of inversion, half of the macrocylic ligand and one anion occupying general positions. Intramolecular N—H...O and N—H...S hydrogen bonding is found between the macrocyclic ligand and the monothiophosphate anion. |
| Databáze: | Directory of Open Access Journals |
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