Crystal structure of tris(2,2′-bipyridine)cobalt(II) bis(1,1,3,3-tetracyano-2-ethoxypropenide)

Autor:	Jamila Benabdallah, Zouaoui Setifi, Fatima Setifi, Habib Boughzala, Abderrahim Titi
Jazyk:	angličtina
Rok vydání:	2019
Předmět:	crystal structure polynitrile ligand ternary systems hydrogen bonding anion...π interactions Crystallography QD901-999
Zdroj:	Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 2, Pp 142-145 (2019)
Druh dokumentu:	article
ISSN:	2056-9890 20569890
DOI:	10.1107/S2056989018018261
Popis:	In the title compound, [Co(C10H8N2)3](C9H5N4O)2, the tris(2,2′-bipyridine)cobalt(II) dication lies across a twofold rotation axes in the space group C2/c. The N atoms of the three bipyridine ligands form a distorted octahedron around the cobalt ion. All the N atoms of the polynitrile 1,1,3,3-tetracyano-2-ethoxypropenide anions participate in C—H...N hydrogen bonds ensuring crystal cohesion and forming a three-dimensional structure. The structure is further stabilized by C—H...π(cation) and anion...π(cation) interactions.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/24e01259a2dd4e4990d3cc2d5bc6316a Zobrazit plný text záznamu View record in DOAJ