Synthesis, Hirshfeld surface analyses and magnetism of a 1D Mn(II) complex
| Autor: | L. Lu, J. Wang, W. P. Wu, X. R. Wu, A. Kumar |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: | |
| Zdroj: | Bulletin of the Chemical Society of Ethiopia, Vol 30, Iss 1, Pp 111-118 (2016) |
| Druh dokumentu: | article |
| ISSN: | 1011-3924 1726-801X |
| DOI: | 10.4314/bcse.v30i1.10 |
| Popis: | A new Mn-based complex of {[Mn(L)2(mi)]·H2O}n (1) (HL = p-hydroxy phenylacetic acid; mi = 1,1’-(1,4-butanediyl)bis(imidazole)), has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 has a dinuclear Mn(II) unit linking by four carboxylate groups. The bridging N-donor ligand with mi links the Mn(II) centers into a 1D double chain. The detailed analyses of Hirschfeld surface and fingerprint plots provide insight into the nature of non-covalent interactions in the title compound. Furthermore, an attempt was made to explain the magnetic property of compound 1 using atoms in molecule (AIM) theory. DOI: http://dx.doi.org/10.4314/bcse.v30i1.10 |
| Databáze: | Directory of Open Access Journals |
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