Autor: |
Masaya Naito, Noriho Taniguchi, Shinobu Miyagawa, Hikaru Takaya, Yuji Tokunaga |
Jazyk: |
angličtina |
Rok vydání: |
2023 |
Předmět: |
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Zdroj: |
Results in Chemistry, Vol 6, Iss , Pp 101164- (2023) |
Druh dokumentu: |
article |
ISSN: |
2211-7156 |
DOI: |
10.1016/j.rechem.2023.101164 |
Popis: |
A chromogenic trefoil-shaped salicylaldehyde azine derivative displayed solvent-dependent isomerism of the C3h and CS symmetries. An azine derivative was prepared from triformylphloroglucinol and 3,5-di-tert-butylsalicylaldehyde hydrazone. The trefoil structure was established using single-crystal X-ray diffraction. UV–vis absorption spectroscopy revealed that solvent-dependent isomerization was accompanied by a bathochromic shift. Isomerization was controlled by adjusting the strength of the intramolecular hydrogen bonding of the azine derivative by solvent polarity. This unusual solvent-dependent isomerization can be utilized for creation azine-based new solvatochromic materials. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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