Fabrication of Na and K based MnO2 nanocomposites for supercapacitive applications

Autor: Priyanka Vashisth, Aditya Sharma, Manas Nasit, Jitendra Pal Singh, Anjali, Mayora Varshney, Shalendra Kumar, S.O. Won, H.J. Shin
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Heliyon, Vol 10, Iss 15, Pp e35360- (2024)
Druh dokumentu: article
ISSN: 2405-8440
DOI: 10.1016/j.heliyon.2024.e35360
Popis: α-Na0.5Mn0.93O2@Na0.91MnO2 (NaMnO) and K0.48Mn1.94O5@Na0.91MnO2 (KNaMnO) nanocomposites have been synthesized using solid-state reaction method. FESEM results convey the formation of column-shaped morphology. FTIR exhibited a shift in the vibration frequency upon potassium loading. Cyclic voltammetric curves are scanned (0 V–0.8 V) at different scan rates (5 mV/s to 100 mV/s) in 1M KOH electrolyte. Galvanostatic charge-discharge characteristics, for different current densities, have shown non-linear or pseudocapacitive characteristics of the prepared electrodes. High specific capacitance of ∼361 F/g and ∼143 F/g, at a current density of 1A/g, has been achieved for KNaMnO and NaMnO samples, respectively. KNaMnO sample exhibited higher capacitive retention (116 %), up to 2000 cycles, and obeys lower series resistance, charge transfer resistance, and Warburg impedance parameters, thus, convey higher efficiency of this compound for supercapacitor applications.
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