Synthesis and crystal structure of NaCuIn(PO4)2
Autor: | Elhassan Benhsina, Jamal Khmiyas, Said Ouaatta, Abderrazzak Assani, Mohamed Saadi, Lahcen El Ammari |
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Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 76, Iss 3, Pp 366-369 (2020) |
Druh dokumentu: | article |
ISSN: | 2056-9890 20569890 |
DOI: | 10.1107/S2056989020001929 |
Popis: | Single crystals of sodium copper(II) indium bis[phosphate(V)], NaCuIn(PO4)2, were grown from the melt under atmospheric conditions. The title phosphate crystallizes in the space group P21/n and is isotypic with KCuFe(PO4)2. In the crystal, two [CuO5] trigonal bipyramids share an edge to form a dimer [Cu2O8] that is connected to two PO4 tetrahedra. The obtained [Cu2P2O12] units are interconnected through vertices to form sheets that are sandwiched between undulating layers resulting from the junction of PO4 tetrahedra and [InO6] octahedra. The two types of layers are alternately stacked along [101] and are joined into a three-dimensional framework through vertex- and edge-sharing, leaving channels parallel to the stacking direction. The channels host the sodium cations that are surrounded by four oxygen atoms in form of a distorted disphenoid. |
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