Cl- and Al-Doped Argyrodite Solid Electrolyte Li6PS5Cl for All-Solid-State Lithium Batteries with Improved Ionic Conductivity
| Autor: | Yeong Jun Choi, Sun-I Kim, Mingyu Son, Jung Woo Lee, Duck Hyun Lee |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Nanomaterials, Vol 12, Iss 24, p 4355 (2022) |
| Druh dokumentu: | article |
| ISSN: | 2079-4991 24618837 |
| DOI: | 10.3390/nano12244355 |
| Popis: | Argyrodite solid electrolytes such as lithium phosphorus sulfur chloride (Li6PS5Cl) have recently attracted great attention due to their excellent lithium-ion transport properties, which are applicable to all-solid-state lithium batteries. In this study, we report the improved ionic conductivity of an argyrodite solid electrolyte, Li6PS5Cl, in all-solid-state lithium batteries via the co-doping of chlorine (Cl) and aluminum (Al) elements. Electrochemical analysis was conducted on the doped argyrodite structure of Li6PS5Cl, which revealed that the substitution of cations and anions greatly improved the ionic conductivity of solid electrolytes. The ionic conductivity of the Cl- and Al-doped Li6PS5Cl (Li5.4Al0.1PS4.7Cl1.3) electrolyte was 7.29 × 10−3 S cm−1 at room temperature, which is 4.7 times higher than that of Li6PS5Cl. The Arrhenius plot of the Li5.4Al0.1PS4.7Cl1.3 electrolyte further elucidated its low activation energy at 0.09 eV. |
| Databáze: | Directory of Open Access Journals |
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