Use of chènevotte, a valuable co-product of industrial hemp fiber, as adsorbent for copper ions: Kinetic studies and modeling

Autor: Chiara Mongioví, Dario Lacalamita, Nadia Morin-Crini, Xavier Gabrion, Vincent Placet, Ana Rita Lado Ribeiro, Aleksandra Ivanovska, Mirjana Kostić, Corina Bradu, Jean-Noël Staelens, Bernard Martel, Marina Raschetti, Grégorio Crini
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Arabian Journal of Chemistry, Vol 15, Iss 4, Pp 103742- (2022)
Druh dokumentu: article
ISSN: 1878-5352
DOI: 10.1016/j.arabjc.2022.103742
Popis: In this study, a series of hemp shives (chènevotte) with different chemical compositions and properties, namely a raw (SHI-R), a washed with water (SHI-W), three samples chemically modified with KOH (SHI-OH), Na2CO3 (SHI-C) or H3PO4 (SHI-H), and a hemp shives sample prepared by grafting of carboxylic groups (SHI-BTCA), were used as adsorbents for the removal of copper present in aqueous solutions. This article presents the abatements and kinetics obtained using batch experiments and their modeling. The results first showed that the quantity of copper removed depended on the used shives and the copper initial concentration. At the same experimental conditions, SHI-C and SHI-BTCA samples possessed similar performances which are significantly higher than those of other studied hemp shives. Copper adsorption reached equilibrium after 60 min of contact time and was independent of concentration in the range 5–150 mg/L for SHI-C and SHI-BTCA. According to the better Chi-squared values, the experimental data were better simulated by the non-linear kinetic model in the order: Lagergren
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